ZHANG Xuefei, YANG Zhao, ZHU Zhiping
The inferior flammability of coal gasification fine slag (CGFS) from entrained-flow gasifiers hampers its resourceful utilization. However, the reasons behind its poor flammability still need to be investigated. This paper conducted a comparative study on the combustion characteristics of three CGFS samples: CGFSGSP, CGFSSN, and CGFSOMB (subscripts GSP, SN, and OMB representing different gasification processes), using experimental techniques such as TG/DTG and combustion kinetic model fitting methods. Additionally, a comprehensive investigation into the physicochemical properties of CGFS was conducted. The objective was to elucidate the causes behind the poor flammability of CGFS. The results revealed that CGFS exhibits lower volatile matter content and higher activation energy than their corresponding raw coal (RC), leading to a significantly higher ignition temperature. The ignition temperatures of RC1, RC2, and RC3 are 361.82°C, 378.66°C, and 404.99°C, respectively. In contrast, the ignition temperatures of CGFSGSP, CGFSSN, and CGFSOMB are 549.08°C, 566.58°C, and 532.67°C, respectively. During the combustion reaction, the temperature (Tmax) at which CGFS reaches its maximum weight loss rate is significantly higher than the temperature (TmaxIII) at which fixed carbon in raw coal reaches its maximum weight loss rate. The TmaxIII of RC1, RC2, and RC3 are 450.90°C, 457.19°C, and 452.77°C, respectively. In contrast, the Tmax of CGFSGSP, CGFSSN, and CGFSOMB are 583.55°C, 608.20°C, and 582.18°C, respectively. The maximum weight loss rate of different types of CGFS is also significantly lower than the fixed carbon combustion maximum weight loss rate of their respective raw coal samples. The physicochemical characterization results of CGFS demonstrate that, compared to the corresponding raw coal, there is a significant reduction in the proportion of active sites in CGFS. Simultaneously, the proportion of C-C/C-H on the surface of residual carbon in CGFS decreases. In contrast, the proportion of O=C-O significantly increases, suggesting a shift toward a more stable state of carbon-containing functional groups. This study is expected to offer essential theoretical support for the efficient combustion utilization of CGFS.