Effect of Operation Parameters on the Thermal Characteristics in a Planar Solid Oxide Fuel Cell

  • WANG Mingyuan ,
  • WANG Ke ,
  • WANG Yongqing ,
  • CHEN Jiangshuai ,
  • AN Bo ,
  • TU Shantung
展开
  • 1. School of Mechanics and Safety Engineering, Zhengzhou University, Zhengzhou 450001, China
    2. Key Laboratory of Process Heat Transfer and Energy Saving of Henan Province, Zhengzhou University, Zhengzhou 450002, China
    3. School of Mechanical and Power Engineering, Zhengzhou University, Zhengzhou 450001, China
    4. Key Laboratory of Pressure Systems and Safety (MOE), East China University of Science & Technology, Shanghai 200237, China

网络出版日期: 2024-09-09

基金资助

The authors are grateful for the supports provided by the Science and Technology Research Program of Henan Province, China (No. 222102320230) and the National Natural Science Foundation of China (No. 51776190).

版权

Science Press, Institute of Engineering Thermophysics, CAS and Springer-Verlag GmbH Germany, part of Springer Nature 2024

Effect of Operation Parameters on the Thermal Characteristics in a Planar Solid Oxide Fuel Cell

  • WANG Mingyuan ,
  • WANG Ke ,
  • WANG Yongqing ,
  • CHEN Jiangshuai ,
  • AN Bo ,
  • TU Shantung
Expand
  • 1. School of Mechanics and Safety Engineering, Zhengzhou University, Zhengzhou 450001, China
    2. Key Laboratory of Process Heat Transfer and Energy Saving of Henan Province, Zhengzhou University, Zhengzhou 450002, China
    3. School of Mechanical and Power Engineering, Zhengzhou University, Zhengzhou 450001, China
    4. Key Laboratory of Pressure Systems and Safety (MOE), East China University of Science & Technology, Shanghai 200237, China

Online published: 2024-09-09

Supported by

The authors are grateful for the supports provided by the Science and Technology Research Program of Henan Province, China (No. 222102320230) and the National Natural Science Foundation of China (No. 51776190).

Copyright

Science Press, Institute of Engineering Thermophysics, CAS and Springer-Verlag GmbH Germany, part of Springer Nature 2024

摘要

固体氧化物燃料电池(SOFC)的有效运行策略可以调整温度梯度的空间分布,从而有利于其长期稳定性。为了研究不同运行条件对 SOFC 内部热行为的影响,本研究建立了一个三维模型,该模型通过与实验数据的比较得到了验证。研究分析了不同工作条件下的发热率及其变化情况,工作电压和气体温度的协同效应被认为是影响温度梯度的关键因素。与原始情况相比,当燃料速度达到 5 m/s 时,SOFC 的温度降低了 21.4 K,但峰值温度梯度增加了 21.2%。同时,较高的燃料速度可以消除约 32% 的温度梯度较大的区域。当氧化剂速度达到 7.5 m/s 时,峰值温度梯度有效降低了 16.59%。同时调整氧化剂速度和燃料速度可以有效降低峰值温度梯度,增加安全区域的面积。本研究阐明了运行条件对电池温度梯度的影响,可为进一步研究 SOFC 的可靠性提供参考。

本文引用格式

WANG Mingyuan , WANG Ke , WANG Yongqing , CHEN Jiangshuai , AN Bo , TU Shantung . Effect of Operation Parameters on the Thermal Characteristics in a Planar Solid Oxide Fuel Cell[J]. 热科学学报, 2024 , 33(5) : 1974 -1989 . DOI: 10.1007/s11630-024-2022-0

Abstract

Effective operation strategies in the solid oxide fuel cell (SOFC) can adjust the spatial distribution of temperature gradient favoring the long-term stability. To investigate the effects of different operating conditions on the thermal behavior inside SOFC, a three-dimensional model is developed in this study. The model is verified by comparing it with the experimental data. The heat generation rate and its variation under different operating conditions are analyzed. The combined effects of operating voltage and gas temperature are considered to be the key factor influencing the temperature gradient. Compared to the original case, the temperature of SOFC decreases by 21.4 K when the fuel velocity reaches 5 m/s. But the maximum temperature gradient increases by 21.2%. Meanwhile, higher fuel velocities can eliminate about 32% of the area with higher temperature gradient. And when the oxidant velocity reaches 7.5 m/s, the peak temperature gradient effectively decreases by 16.59%. Simultaneous adjustment of the oxidant and fuel velocities can effectively reduce the peak temperature gradient and increase the safety zone. The effects of operation conditions on the temperature gradient of the cell are clarified in this study, which can be a reference for further research on the reliability of SOFCs.

参考文献

[1] Li D.D., Zhao H.X., Kong F.C., et al., Application of ejector in solid oxide fuel cell anode circulation system. Journal of Thermal Science, 2022, 31(3): 634–649.
[2] Zeng Z.Z., Qian Y.P., Zhang Y.J., et al., A review of heat transfer and thermal management methods for temperature gradient reduction in solid oxide fuel cell (SOFC) stacks. Applied Energy, 2020, 280: 115899.
[3] Deng M.L., Liu J.Y., Zhang X.S., et al., Energy and parameter analysis of SOFC system for hydrogen production from methane steam reforming. Journal of Thermal Science, 2022, 31(6): 2088–2110.
[4] Patcharavorachot Y., Arpornwichanop A., Chuachuensuk A., Electrochemical study of a planar solid oxide fuel cell: Role of support structures. Journal of Power Sources, 2008, 177(2): 254–261.
[5] Raj A., Sasmito A.P., Shamim T., Numerical investigation of the effect of operating parameters on a planar solid oxide fuel cell. Energy Conversion and Management, 2015, 90: 138–145.
[6] Wang Y., Zhan R.B., Qin Y.Z., et al., Three-dimensional modeling of pressure effect on operating characteristics and performance of solid oxide fuel cell. International Journal of Hydrogen Energy, 2018, 43(43): 20059–20076.
[7] Fu P., Yang J., Wang Q.W., Numerical study on mass transfer and electrical performance of anode-supported planar solid oxide fuel cells with gradient porosity anode. Journal of Heat Transfer, 2020, 142(2): 022101.
[8] Zhang X.Q., Espinoza M., Li T.S., et al., Parametric study for electrode microstructure influence on SOFC performance. International Journal of Hydrogen Energy, 2021, 46(75): 37440–37459.
[9] Danilov V. A., Tade M. O., A CFD-based model of a planar SOFC for anode flow field design. International Journal of Hydrogen Energy, 2009, 34(21): 8998–9006.
[10] Zhan R.B., Wang Y., Ni M., et al., Three-dimensional simulation of solid oxide fuel cell with metal foam as cathode flow distributor. International Journal of Hydrogen Energy, 2020, 45(11): 6897–6911.
[11] Wang Y.Q., Chen J.S., Liu K.L., et al., Computational screening of La2NiO4+delta cathodes with Ni site doping for solid oxide fuel cells. Inorganic Chemistry, 2023, 62(19): 7574–7583.
[12] Hao C.K., Zeng Z.Z., Zhao B.G., et al., Local heat generation management for temperature gradient reduction in tubular solid oxide fuel cells. Applied Thermal Engineering, 2022, 211: 118453.
[13] Fan P.F., Li G.J., Zeng Y.K., et al., Numerical study on thermal stresses of a planar solid oxide fuel cell. International Journal of Thermal Sciences, 2014, 77: 1–10.
[14] Xu M., Li T. S., Yang M., et al., Modeling of an anode supported solid oxide fuel cell focusing on thermal stresses. International Journal of Hydrogen Energy, 2016, 41(33): 14927–14940.
[15] Shao Q., Bouhala L., Fiorelli D., et al., Influence of fluid flow and heat transfer on crack propagation in SOFC multi-layered like material with anisotropic porous layers. International Journal of Solids and Structures, 2016, 78–79: 189–198.
[16] Shao Q., Fernández-González R., Ruiz-Morales J.C., et al., An advanced numerical model for energy conversion and crack growth predictions in solid oxide fuel cell units. International Journal of Hydrogen Energy, 2015, 40(46): 16509–16520.
[17] Luo Y., Jiang W.C., Zhang Q., et al., Effects of anode porosity on thermal stress and failure probability of planar solid oxide fuel cell with bonded compliant seal. International Journal of Hydrogen Energy, 2016, 41(18): 7464–7474.
[18] Fang X.R., Lin Z.J., Numerical study on the mechanical stress and mechanical failure of planar solid oxide fuel cell. Applied Energy, 2018, 229: 63–68.
[19] Wu Y.Y., Shi Y.X., Cai N.S., et al., Thermal modeling and management of solid oxide fuel cells operating with internally reformed methane. Journal of Thermal Science, 2018, 27(3): 203–212.
[20] Serincan M.F., Pasaogullari U., Singh P., Controlling reformation rate for a more uniform temperature distribution in an internal methane steam reforming solid oxide fuel cell. Journal of Power Sources, 2020, 468: 228310.
[21] Zhang Z.Q., Wang Y.L., Ba L., Analysis of heat and mass transfer for a single-planar-anode-supported solid oxide fuel cell considering internal reforming. Journal of Thermal Science, 2019, 29(3): 697–707.
[22] Huang C.M., Shy S.S., Lee C.H., On flow uniformity in various interconnects and its influence to cell performance of planar SOFC. Journal of Power Sources, 2008, 183(1): 205–213.
[23] Ramírez-Minguela J.J., Alfaro-Ayala J.A., Rangel-Hernández V.H., et al., Numerical analysis of the effect of trapezoidal baffles inside fuel and air channels on the performance of a planar-type solid oxide fuel cell. Journal of Thermal Science and Engineering Applications, 2022, 14(4): 041004.
[24] Lee H.M., Yuan P., Liu S.F., Thermal and electrical analysis in a solid oxide fuel cell stack using a curved profile for the inlet flow rate along the stacking direction. International Journal of Green Energy, 2014, 12(2): 117–124.
[25] Yuan P., Liu S.F., Effect of non-uniform inlet flow rate on the heat-up process of a solid oxide fuel cell unit with cross-flow configuration. International Journal of Hydrogen Energy, 2016, 41(28): 12377–12386.
[26] Zhang Z.G., Yue D.T., Yang G.G., et al., Three-dimensional CFD modeling of transport phenomena in multi-channel anode-supported planar SOFCs. International Journal of Heat and Mass Transfer, 2015, 84: 942–954.
[27] Choudhary T., Sanjay, Computational analysis of IR-SOFC: Thermodynamic, electrochemical process and flow configuration dependency. International Journal of Hydrogen Energy, 2016, 41(2): 1259–1271.
[28] Lee S., Kim H., Yoon K.J., et al., The effect of fuel utilization on heat and mass transfer within solid oxide fuel cells examined by three-dimensional numerical simulations. International Journal of Heat and Mass Transfer, 2016, 97: 77–93.
[29] Kim D.H., Bae Y., Lee S., et al., Thermal analysis of a 1-kW hydrogen-fueled solid oxide fuel cell stack by three-dimensional numerical simulation. Energy Conversion and Management, 2020, 222: 113213.
[30] Zheng K.Q., Sun Y., Shen S.L., et al., A novel cooler for the thermal management of solid oxide fuel cell stack. Sustainable Energy Technologies and Assessments, 2021, 48: 101564.
[31] Zeng Z.Z., Hao C.K., Zhao B.G., et al., Local heat transfer enhancement by recirculation flows for temperature gradient reduction in a tubular SOFC. International Journal of Green Energy, 2021, 19(10): 1132–1147.
[32] Xu H.R., Ma J.B., Tan P., et al., Towards online optimisation of solid oxide fuel cell performance: Combining deep learning with multi-physics simulation. Energy and AI, 2020, 1: 100003.
[33] Wang C., He Q.J., Li Z., et al., Modelling of solid oxide fuel cells with internal glycerol steam reforming. International Journal of Hydrogen Energy, 2022, 47(33): 15012–15023.
[34] Aman N.A.M.N., Muchtar A., Rosli M.I., et al., Influence of thermal conductivity on the thermal behavior of intermediate-temperature solid oxide fuel cells. Journal of Electrochemical Science and Technology, 2020, 11(2): 132–139.
[35] Shen Q.W., Li S.A., Yang G.G., et al., Analysis of heat and mass transport characteristics in anode-supported solid oxide fuel cells at various operating conditions. Numerical Heat Transfer, Part A: Applications, 2019, 75(8): 509–522.
[36] Xu Q.D., Xia L.C., He Q.J., et al., Thermo-electrochemical modelling of high temperature methanol-fuelled solid oxide fuel cells. Applied Energy, 2021, 291: 116832.
[37] Lee S., Park M., Kim H., et al., Thermal conditions and heat transfer characteristics of high-temperature solid oxide fuel cells investigated by three-dimensional numerical simulations. Energy, 2017, 120: 293–305.
[38] Khazaee I., Rava A., Numerical simulation of the performance of solid oxide fuel cell with different flow channel geometries. Energy, 2017, 119: 235–244.
[39] Park J., Kim D., Baek J., et al., Effect of electrolyte thickness on electrochemical reactions and thermo-fluidic characteristics inside a SOFC unit cell. Energies, 2018, 11(3): 473–487.
[40] Daun K.J., Beale S.B., Liu F., et al., Radiation heat transfer in planar SOFC electrolytes. Journal of Power Sources, 2006, 157(1): 302–310.
[41] Wang M.Y., Wang K., Wang Y.Q., et al., Analysis of mass transfer characteristics in a planar solid oxide fuel cell with a chaotic flow channel. Journal of Electroanalytical Chemistry, 2024, 956: 118071.
[42] Celik A.N., Three-dimensional multiphysics model of a planar solid oxide fuel cell using computational fluid dynamics approach. International Journal of Hydrogen Energy, 2018, 43(42): 19730–19748.
[43] Kakac S., Pramuanjaroenkij A., Zhou X.Y., A review of numerical modeling of solid oxide fuel cells. International Journal of Hydrogen Energy, 2007, 32(7): 761–786.
[44] Hafsia A., Bariza Z., Djamel H., et al., SOFC fuel cell heat production: Analysis. Energy Procedia, 2011, 6: 643–650.
[45] Aguiar P., Adjiman C.S., Brandon N. P., Anode-supported intermediate-temperature direct internal reforming solid oxide fuel cell. Journal of Power Sources, 2005, 147: 136–147.
[46] Wang Y.Q., Li X.C., Guo Z.N., et al., Effect of the reactant transportation on performance of a planar solid oxide fuel cell. Energies, 2021, 14(4): 1212–1225.
文章导航

/