Analysis and Modeling of Calendar Aging and Cycle Aging of LiCoO2/Graphite Cells

  • WANG Wei ,
  • YUAN Baoqiang ,
  • SUN Qie ,
  • WENNERSTEN Ronald
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  • 1. Institute of Thermal Science and Technology, Shandong University, Ji’nan 250061, China
    2. School of Energy and Power Engineering, Shandong University, Ji’nan 250061, China
    3. Institute for Advanced Science and Technology, Shandong University, Ji’nan 250061, China

网络出版日期: 2024-04-30

基金资助

This work was supported by Shandong University Seed Fund Program for International Research Cooperation.

版权

Science Press, Institute of Engineering Thermophysics, CAS and Springer-Verlag GmbH Germany, part of Springer Nature 2024

Analysis and Modeling of Calendar Aging and Cycle Aging of LiCoO2/Graphite Cells

  • WANG Wei ,
  • YUAN Baoqiang ,
  • SUN Qie ,
  • WENNERSTEN Ronald
Expand
  • 1. Institute of Thermal Science and Technology, Shandong University, Ji’nan 250061, China
    2. School of Energy and Power Engineering, Shandong University, Ji’nan 250061, China
    3. Institute for Advanced Science and Technology, Shandong University, Ji’nan 250061, China

Online published: 2024-04-30

Supported by

This work was supported by Shandong University Seed Fund Program for International Research Cooperation.

Copyright

Science Press, Institute of Engineering Thermophysics, CAS and Springer-Verlag GmbH Germany, part of Springer Nature 2024

摘要

当前,锂离子电池已被广泛应用于各种领域。然而,它们受到由日历老化和循环老化导致的容量衰减问题的困扰。本研究通过对钴酸锂/石墨电池在不同存储温度和不同充放电状态范围下进行存储和循环实验,探究了储存时间、温度和不同深度的充放电循环对锂离子电池容量衰减的影响。根据测量数据,提出了单组分和双组分老化模型,分别描述了日历老化和循环老化引起的容量衰减。钴酸锂/石墨电池的日历老化主要受到存储期间温度和荷电状态的影响,循环老化主要受到平均荷电状态和荷电状态变化的影响。

本文引用格式

WANG Wei , YUAN Baoqiang , SUN Qie , WENNERSTEN Ronald . Analysis and Modeling of Calendar Aging and Cycle Aging of LiCoO2/Graphite Cells[J]. 热科学学报, 2024 , 33(3) : 1109 -1118 . DOI: 10.1007/s11630-024-1918-z

Abstract

Lithium-ion batteries are used in a wide range of applications. However, their cycle life suffers from the problem of capacity fade, which includes calendar and cycle aging. The effects of storage time, temperature and partial charge-discharge cycling on the capacity fade of Li-ion batteries are investigated in this study. The calendar aging and cycle aging are presented based on the storage and cycling experiment on LiCoO2/graphite cells under different storage temperature and different ranges of state of charge (SOC). Based on the measurement data, a one-component and a double-component aging model are presented to respectively describe the capacity fade caused by calendar and cycle aging. The calendar aging of LiCoO2/graphite batteries is mainly affected by temperature and SOC during the storage. Mean SOC and change in SOC (∆SOC) are the main factors affecting battery degradation during cycling operation.

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