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An In-Situ MRI Method for Quantifying Temperature Changes during Crystal Hydrate Growths in Porous Medium

  • ZHANG Lunxiang ,
  • SUN Mingrui ,
  • WANG Tian ,
  • YANG Lei ,
  • ZHANG Xiaotong ,
  • ZHAO Jiafei ,
  • SONG Yongchen
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  • 1. Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, School of Energy and Power Engineering, Dalian University of Technology, Dalian 116024, China
    2. Interdisciplinary Institute of Neuroscience and Technology, Zhejiang University, Hangzhou 310029, China

网络出版日期: 2023-12-01

基金资助

This work is supported by the National Natural Science Foundation of China (Grant Nos. 52025066, 52006024, 81701774, 61771423, U21B2065) and the Fundamental Research Funds for the Central Universities (Grant No. DUT22LAB130).

版权

Science Press, Institute of Engineering Thermophysics, CAS and Springer-Verlag GmbH Germany, part of Springer Nature 2022

An In-Situ MRI Method for Quantifying Temperature Changes during Crystal Hydrate Growths in Porous Medium

  • ZHANG Lunxiang ,
  • SUN Mingrui ,
  • WANG Tian ,
  • YANG Lei ,
  • ZHANG Xiaotong ,
  • ZHAO Jiafei ,
  • SONG Yongchen
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  • 1. Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, School of Energy and Power Engineering, Dalian University of Technology, Dalian 116024, China
    2. Interdisciplinary Institute of Neuroscience and Technology, Zhejiang University, Hangzhou 310029, China

Online published: 2023-12-01

Supported by

This work is supported by the National Natural Science Foundation of China (Grant Nos. 52025066, 52006024, 81701774, 61771423, U21B2065) and the Fundamental Research Funds for the Central Universities (Grant No. DUT22LAB130).

Copyright

Science Press, Institute of Engineering Thermophysics, CAS and Springer-Verlag GmbH Germany, part of Springer Nature 2022

摘要

多孔介质内晶体相变涉及热力学、流体力学、化学等多过程耦合,其相变伴随产生的温度变化是探明晶体生长与分解过程传热特性必不可少的重要参数。目前,常规热电偶测温仅适用于分布式点温分析且容易破坏样品、红外热感成像非常受限于被检测样品的透明程度,亟需发展一种多孔介质内原位测温技术。因此,本文基于氢质子化学位移的温度依赖特性,利用9.4 T 1H核磁共振成像系统,首次开发了适用于多孔介质内的3D GRE脉冲序列与核磁测温方法,同步获取了水合物晶体分解过程的幅值图与相位图,反演得到水饱和度、水合物饱和度以及温度场的时间与空间变化,该研究结果对于优化水合物相变过程,比如天然气水合物开采、水合物蓄冷技术利用具有重要意义。

本文引用格式

ZHANG Lunxiang , SUN Mingrui , WANG Tian , YANG Lei , ZHANG Xiaotong , ZHAO Jiafei , SONG Yongchen . An In-Situ MRI Method for Quantifying Temperature Changes during Crystal Hydrate Growths in Porous Medium[J]. 热科学学报, 2022 , 31(5) : 1542 -1550 . DOI: 10.1007/s11630-022-1674-x

Abstract

Given the complexity of the thermo-hydro-chemically coupled phase transition process of hydrates, real-time in-situ observations are required. Thermometry maps are particularly essential in analyzing the heat transfer process during the growth and dissociation of crystal hydrates. In this study, we present the temporally and spatially resolved thermometry of the formation of tetrahydrofuran hydrates based on the temperature dependence of the chemical shift of the water proton. Images of temperature changes were synchronously obtained using a 9.4 T 1H magnetic resonance imaging (MRI) system to predict the saturation level of the aqueous solution, phases of the solid hydrates, and the positive temperature anomaly of the exothermic reaction. It was observed that variations in the MRI signal decreased while the temperature rise differed significantly in space and time. The results predicted in this study could have significant implications in optimizing the phase transition process of gas hydrates.

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